When I looked up the Super Start Group 31, the specs I found said it's a 105 AH battery rated at 210 minutes of RC. The Harris Professional shows 140 minutes of RC and is likely about 80-85 AH. So in theory the two Group 24s should give more capacity. In reality, I suspect you'll get very similar performance from two of the Group 24 vs one of the Group 31. You could use one of each in a parallel setup for slightly more capacity but this would put a heavy load on the smaller battery and might lead to overcharging/boiling. I wouldn't do that personally but you could choose to if you're planning to replace them soon anyway and the present setup doesn't give you enough capacity for your planned trips.
Reserve capacity (RC) isn't really a very good prediction of deep cycle battery performance in RVs since it is measured at 25 A discharge rate which is well above the DC load in a typical RV. Lots of good info on this topic at Battery University. Here's one link:
https://batteryuniversity.com/articl...asure-capacity