They are not reusable, Just clip them with a side cutter.
If you go with PEX fittings, be aware there are two sizes. RV PEX is slightly smaller than than crimp rings for irrigation, even thou they both will say 1/2"
You have a few options, can go with SharkBite, Watts, or in the PEX section you can pick up a replacement brass valve. I used Watts, to replace my low point drain valves last year.
I too have a leaky water heater valve, I have been dealing with for the last 2 years (tiny drip). I have not decided which way I am going yet.
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