I've never had an issue adding septic treatment to a tank with pink anti freeze. If there was off gassing it should go through the roof vent and would likely not be perceptible. I'm in a similar situation as you from a temp stand point. I'm adding pink antifreeze to the tank now to mix with and keep the water that won't drain from freezing. Once I get to the camp sight & use the toilet the first time, I'll add the black tank treatment.
The problem isn't freezing in the tank itself. The issue is the water freezing next to your drain valve and causing it to break. Technically, to do it right in this situation, you should add pink antifreeze directly after the last tank dump. That way it is right next to the drain. Any water you add after that would have to mix.
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2017 Seismic 4114
2016 Chevrolet 3500 CC, DD DRW
1 Wife, 2 Kids under 12
Camping nights: 2019 - Too many to count, 2020 - 3
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