Do you have a battery disconnect/shutoff switch connected to you battery? If so, try removing it and connecting the positive and negative leads directly to the battery.
I recently had a similar issue to what you described. Everything worked fine on 120AC but on 12DC only the LED interior lights worked. Despite a fully charged battery, the slide out, awning, and power jack would not work. After a lot of trouble shooting, I figured out the switch on the battery box for the power disconnect/shut off had went bad and was only allowing just enough power to operate the lights but not enough for the bigger items.
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